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title Arsenic fractionation in agricultural acid soils from NW Spain using a sequential extraction procedure
authors Novoa-Munoz, JC; Queijeiro, JMG; Blanco-Ward, D; Alvarez-Olleros, C; Garcia-Rodeja, E; Martinez-Cortizas, A
author full name Novoa-Munoz, Juan Carlos; Queijeiro, Jose Manuel G.; Blanco-Ward, Daniel; Alvarez-Olleros, Cristalina; Garcia-Rodeja, Eduardo; Martinez-Cortizas, Antonio
title Arsenic fractionation in agricultural acid soils from NW Spain using a sequential extraction procedure
nationality nacional
source SCIENCE OF THE TOTAL ENVIRONMENT
language English
document type Article
author keywords agricultural soils; vineyard; arsenic; sequential extraction; soil use change
keywords plus CONTAMINATED SOILS; AZNALCOLLAR; SPILL
abstract Arsenic fractionation has been studied in nine vineyard soils from a wine-producing area in Galicia (NW Spain) characterized by an unusually high As content. Total As concentrations are 7 to 10 times higher the maximum values allowed by the legislation, reaching maximum value of 200 mg kg(-1). The study of As fractionation revealed that those fractions showing strong correlations to crystalline Fe and Al hydrous oxides (r > 0.69, p < 0.01 and r > 0.71, p < 0.01 respectively) represented, on average, higher than the 80% of total As. The low levels of mobile and potentially toxic As fractions (< 4% of total As) suggest that its toxicity is partially minimized in these soils, although the modifications induced by soil management could promote an increase of As availability.(c) 2007 Elsevier B.V. All rights reserved.
author address Univ Vigo, Fac Ciencias Ourense, Area Edafol & Quim Agr, Orense 32004, Spain; Univ Santiago de Compostela, Fac Biol, Dept Edafol & Quim Agr, Santiago 15782, Spain
reprint address Novoa-Munoz, JC (reprint author), Univ Vigo, Fac Ciencias Ourense, Area Edafol & Quim Agr, As Lagoas S-N, Orense 32004, Spain.
e-mail address edjuanca@uvigo.es
researcherid number Novoa-Munoz, Juan Carlos/A-9181-2009; Queijeiro, Jose/L-7565-2014; Martinez Cortizas, Antonio/M-6196-2015
orcid number Novoa-Munoz, Juan Carlos/0000-0003-3062-4191; Queijeiro, Jose/0000-0003-2471-1563; Martinez Cortizas, Antonio/0000-0003-0430-5760
cited references Adriano DC, 2001, TRACE ELEMENTS TERRE; BELZILE N, 1989, ENVIRON SCI TECHNOL, V23, P1015, DOI 10.1021/es00066a014; Brandstetter A, 2000, REMEDIATION ENGINEERING OF CONTAMINATED SOILS, P715; Garcia-Rodeja E, 2004, CATENA, V56, P155, DOI 10.1016/j.catena.2003.10.009; Lombi E, 2000, WATER AIR SOIL POLL, V124, P319, DOI 10.1023/A:1005230628958; Lumsdon DG, 2001, APPL GEOCHEM, V16, P571, DOI 10.1016/S0883-2927(00)00063-9; PEREZ DR, 1991, MINERIA GALICIA CONS; Sadiq M, 1997, WATER AIR SOIL POLL, V93, P117, DOI 10.1023/A:1022135909197; Simon M, 1999, SCI TOTAL ENVIRON, V242, P105, DOI 10.1016/S0048-9697(99)00378-2; Taggart MA, 2004, SCI TOTAL ENVIRON, V323, P137, DOI 10.1016/j.scitotenv.2003.10.008; Wenzel WW, 2001, ANAL CHIM ACTA, V436, P309, DOI 10.1016/S0003-2670(01)00924-2
cited reference count 11
times cited 11
total times cited count (wos, bci, and cscd) 12
publisher ELSEVIER SCIENCE BV
publisher city AMSTERDAM
publisher address PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
issn 0048-9697
29-character source abbreviation SCI TOTAL ENVIRON
iso source abbreviation Sci. Total Environ.
publication date MAY 25
year published 2007
volume 378
issue 1-2
beginning page 18
ending page 22
digital object identifier (doi) 10.1016/j.scitotenv.2007.01.026
page count 5
web of science category Environmental Sciences
subject category Environmental Sciences & Ecology
document delivery number 174NM
unique article identifier WOS:000246949000004
CESAM authors